中文核心期刊
中国科技核心期刊
中国化学与物理电源行业协会会刊
中国电子学会化学与物理电源分会会刊
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20 April 2025, Volume 49 Issue 4
    

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  • WANG Yan, BAI Xintao, LIU Hairui, TIAN Yuan, ZHANG Qingxu
    Chinese Journal of Power Sources. 2025, 49(4): 685-690. https://doi.org/10.3969/j.issn.1002-087X.2025.04.001
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Traditional thermal battery uses metal sulfide as cathode material. With the increasing demand for high energy density of battery, the need for high-voltage new cathode has become more and more urgent, and the application of high voltage cathode in thermal battery is being explored at home and abroad. In this paper, the research progress of halide and oxide cathode was reviewed, the latest experimental results were reported, and the problems and optimization directions were summarized.
  • ZHANG Yongxian, QIAN Sensen, YANG Peng, LIU Xiaowei
    Chinese Journal of Power Sources. 2025, 49(4): 691-698. https://doi.org/10.3969/j.issn.1002-087X.2025.04.002
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    NaTi2(PO4)3 has a NASICON stable structure, an ultra-large three-dimensional open architecture, significant energy density and stability, and has become a hotly researched anode material for aqueous sodium-ion batteries (ASIBs). However, NaTi2(PO4)3 has many problems in ASIBs, such as poor conductivity, side effects with water, and material dissolution. In order to overcome the above problems, nano-materialization, carbon covering, and element doping was usually used to solve the above problems, so as to optimize the performance of the material and make it have high-conductivity and long-cycle performance. This article reviewed the structure, modification method and electrochemical performance of NaTi2(PO4)3 materials to deepen the understanding of the improvement of the NaTi2(PO4)3 structure and the performance optimization technical path and method.
  • LV Dongxiang, LI Xuan, ZHOU Tian, CHEN Yuanyuan
    Chinese Journal of Power Sources. 2025, 49(4): 699-705. https://doi.org/10.3969/j.issn.1002-087X.2025.04.003
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    The radioisotope nuclear power source is a device that converts the energy released by the decay of radioactive isotopes into electrical energy. The development and present status of radioactive isotope source and the energy conversion device were reviewed. The radioisotope sources that can be selected for use include plutonium-238, strontium-90, americium-241, nickel-63, and tritium were presented. The energy conversion technologies and energy conversion devices were expatiated according to the way of energy conversion. The use of suitable radioactive isotopes to prepare the power source has advantages that are unmatched by conventional power sources, such as a long service life, no constraints from external environments, and no maintenance. As a self-sustaining power source, radioisotope nuclear power sources have an indispensable role in harsh environments such as no light, weak light, low temperature. The present situation of radioisotope nuclear power source was introduced in the military and medical applications. The direction of technology development and the application prospects of product were envisioned.
  • Research and design: Chemicalpower sources
  • ZHAOYangyang, AN Xiangli, XU Yunjun, CHENG Di, GONG Lele, YAN Rui, WEN Wanchao
    Chinese Journal of Power Sources. 2025, 49(4): 706-714. https://doi.org/10.3969/j.issn.1002-087X.2025.04.004
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    The relative scarcity of domestic cobalt resources, mostly relying on imports, de-cobaltization has become one of the future development directions of ternary cathode materials for lithium-ion batteries. In this study, high-nickel cobalt-free LiNi0.9Mn0.1O2 binary single crystal cathode material and cobalt-containing LiNi0.92Co0.06Mn0.02O2 ternary single crystal cathode material were taken as the objects of study, and the electrochemical performances such as specific capacity, initial DCR, rate and cycling of the two materials were characterized using CR2016 button half battery and 604062 soft pack full battery respectively. The feasibility of the high-nickel cobalt-free binary single crystal cathode material in the application of lithium-ion batteries was investigated. The experimental results show that although the specific capacity of high-nickel cobalt-free LiNi0.9Mn0.1O2 binary single crystal cathode material is slightly lower than that of cobalt-containing LiNi0.92Co0.06Mn0.02O2 ternary single crystal cathode material, it has obvious advantages in terms of cycle stability. And it can be used as one of the substitutes of the cobalt ternary cathode material when the price of cobalt is unstable in the future.
  • GUO Wangzhong, YU Baojun, CHEN Chao
    Chinese Journal of Power Sources. 2025, 49(4): 715-719. https://doi.org/10.3969/j.issn.1002-087X.2025.04.005
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    Silicon anodes has attracted widespread attention due to its extremely high specific capacity. Only minor amounts of Si added in the anode can significantly improve batteries specific capacity, but the huge volume expansion will limit its stability. In full-cells, the utilization rate of anode can be adjusted by changing the N/P ratio, and the lithium insertion depth of the silicon anode can be controlled, thereby changing its energy density and cycling performance. In this work,we produced pouch Li-ion batteries with three N/P ratios of 1.09, 1.06, and 1.03. As the N/P ratio decreased, the battery quality decreased, the total silicon content decreased, the energy density and initial coulombic efficiency of the battery increased. However, during the cycling process, the lithium insertion and extraction depth of the silicon increased, and the volume expansion intensified, ultimately leading to a shortened cycling life. Therefore, introducing silicon into the LFP system and designing an appropriate N/P ratio is expected to improve the energy density of LFP system to 200 Wh/kg at the cost of cycle life.
  • LI Shuli, CHEN Shipeng, ZHANG Lingli
    Chinese Journal of Power Sources. 2025, 49(4): 720-726. https://doi.org/10.3969/j.issn.1002-087X.2025.04.006
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    Li+ de-solvation at the solid electrolyte interphase (SEI) is a critical step governing the fast charging and low-temperature performance of lithium-ion batteries. The Li3P, LiF, and Li3PO4 interfacial phases were designed on graphite anode by liquid-phase coating, respectively, which promoted the de-solvation of Li+ and constructed an inorganic-rich SEI membrane, thus accelerating the Li+ transport at the electrode interfaces and between the interfaces. From the EIS impedance, it can be clearly found that the low-temperature internal resistance is significantly reduced with the addition of the additive LiF compared with conventional graphite. The battery using PHG-Q anode can guarantee 49.57% charging capacity share at -20 ℃@0.2 C. At -40 ℃@0.2 C, the charging capacity share is improved by 7.29% with conventional graphite. Cycling LiF additives at low temperature -40 ℃@0.05 C facilitates Li+ de-solvation effect, and the capacity retention rate can be maintained at 93.95% for 800 cycles.
  • WANG Jiaojiao, TIAN Yumeng, ZHAO Bintao, ZHANG Yue, ZENG Tao
    Chinese Journal of Power Sources. 2025, 49(4): 727-732. https://doi.org/10.3969/j.issn.1002-087X.2025.04.007
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    Uncoordinated solvents were used as fast-charging additives in lithium-ion batteries. Two kinds of reagents with common structure were selected, namely hexafluorobenzene (HFB) and pentafluorophenyl trifluoroacetate (PFTF). From the perspective of HFB and PFTF's own structure, the differences in the regulation ways of interfacial solvation structure and the resulting differences in the degree of solvation were analyzed. The effects of the two on the fast charge and low temperature performance of lithium-ion batteries were sorted out.
  • DING Shuang, LIU Lian, ZHOU Jiang
    Chinese Journal of Power Sources. 2025, 49(4): 733-739. https://doi.org/10.3969/j.issn.1002-087X.2025.04.008
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    Using density functional theory based on first-principles, theoretical calculations were conducted on the modification of lithium manganese phosphate (LiMnPO4) materials. Compared with LiFePO4, LiMnPO4 offers a higher voltage with a comparable specific capacity, but it suffers from low electrical conductivity and lithium-ion diffusion coefficients, resulting in poor electrochemical performance. Therefore, this paper aimed to enhance the electrochemical performance of LiMnPO4 materials through doping modification, achieving a balance between high energy density and high safety. The evaluation indicators include volume change, electronic conductivity, voltage, lithium-ion diffusion, and thermodynamic stability. Five elements, namely Fe, Co, Ni, Nb, and Ti, were selected for doping modification. After doping with heterologous elements, the band gap of the materials decreased, leading to improved electronic conductivity. Ni and Co doping increased the voltage of Li-MnPO4 but compromised the material's safety. According to the radar chart of the five evaluation indicators, Fe doping exhibits the best overall performance. Based on lithium iron manganese phosphate, Ni and Co were selected for dual-element doping modification as the second dopant. Compared with Ni doping, Co doping further improves the electronic conductivity of the material.
  • CHEN Zhixuan, WANG Hao, LU Lingxia, HUA Sicong, HE Jiarui, YU Miao
    Chinese Journal of Power Sources. 2025, 49(4): 740-749. https://doi.org/10.3969/j.issn.1002-087X.2025.04.009
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    The state of charge (SOC) of lithium-ion battery plays a crucial role in battery balancing, energy usage optimizing, etc. To address the issue of heavy computational burden caused by the nonlinearity of state-space equations in model-based SOC estimation methods, gated recurrent units (GRU) was used for soft sensing of SOC. Then linear state-space equations were constructed by using the measured SOC as an output variable and the Kalman filter (KF) was applied to estimate SOC. Under random driving cycles, the proposed method achieves a maximum absolute error of 0.017 in SOC estimation, while also offering fast estimation speed. Further study indicates that there are significant differences in the parameters of battery models under different charging and discharging rates, leading to lower SOC estimation accuracy of model-based methods in complex conditions. In contrast, the proposed GRU-KF method, due to its independence from precise battery models, demonstrates better adaptability to complex conditions.
  • LI Jinhan, LIU Shuaibang, WANG Wenwei, YANG Xiaoguang
    Chinese Journal of Power Sources. 2025, 49(4): 750-754. https://doi.org/10.3969/j.issn.1002-087X.2025.04.010
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    The electrochemical energy storage materials inside a battery exhibit significant changes in their mechanical properties, such as thickness and stiffness, during the charge and discharge processes. The stiffness of components affects the mechanical characteristics, lifespan, and safety of the entire vehicle, making it crucial to study the equivalent stiffness variation of lithium-ion batteries during charging and discharging. This paper proposed a dynamic measurement method for the equivalent stiffness of lithium-ion batteries. By measuring the free expansion thickness of the battery and the pressure under given constraint conditions, the equivalent stiffness of the lithium-ion battery during the charging and discharging process was obtained. The experimental results show that when the preload force is between 800 and 1 800 N, the equivalent stiffness of the experimental battery ranges from 13 550 to 27 550 N/mm. Furthermore, the equivalent stiffness of the battery is larger under higher pressure and lower states of charge (SOC). The method proposed in this paper can be further extended to obtain the stiffness throughout the entire lifecycle of the battery, providing guidance for the safe design of lithium-ion batteries.
  • ZHANG Hanzhao, ZHAO Yicong, DAI Bingfei, ZHANG Yonghui, GAO Peng
    Chinese Journal of Power Sources. 2025, 49(4): 755-763. https://doi.org/10.3969/j.issn.1002-087X.2025.04.011
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    Electrochemical impedance spectroscopy (EIS) is one of the important parameters reflecting the performance of lithium-ion batteries, and the EIS can be used for online assessment of lithium battery working condition and fault warning. For the online monitoring of electrochemical impedance spectra of lithium-ion batteries, an EIS online monitoring system based on an embedded microcontroller, a battery management IC and upper computer software, was designed. This system is able to collect the wide-band impedance characteristics of lithium-ion batteries and realize the online measurement of AC impedance in the frequency range of 0.12-7 812.52 Hz. The maximum relative impedance deviation is only 0.61% (@0.48 Hz) by five repetitive tests on lithium-ion batteries. The EIS static tests of lithium-ion batteries at different SOCs were performed using this system and electrochemical workstation respectively, and the maximum relative error is only 5.91% (@7 812.52 Hz, 30% SOC). Through the dynamic tracking of the battery working conditions, the dynamic curve of EIS during charging and discharging was analyzed, and it is proposed that the amplitude change rate of 0.61 mΩ/s was taken as the threshold value of the battery over-discharge, which can be carried out in advance of 180 s for the early warning of over-discharge. This EIS online monitoring system designed has the advantages of data visualization, simple hardware structure, high detection efficiency and low cost, which can be easily integrated into the battery management system (BMS), and has the prospect of application in the online estimation of the state of lithium-ion batteries and early warning of failures.
  • DOU Yuanyun, ZHANG Chengzhi, FENG Juqiang
    Chinese Journal of Power Sources. 2025, 49(4): 764-771. https://doi.org/10.3969/j.issn.1002-087X.2025.04.012
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    Addressing the challenge of state of charge (SOC) estimation faced by lithium-ion batteries in mining applications, this paper proposed a novel approach that combines recurrent neural networks (RNN) with adaptive unscented Kalman filtering (AUKF). This method takes into account the influence of multiple factors, such as temperature and rate, on SOC estimation. Multi-factor impact tests were conducted on a 228 Ah high-capacity lithium-ion battery for mining applications, leading to the development of an improved first-order RC equivalent circuit model. RNN regression was utilized to analyze the impact of multiple factors on the SOC-open circuit voltage (OCV) relationship and model parameters. The AUKF algorithm was employed to effectively identify the battery model and estimate the SOC under various complex operating conditions. The experimental results demonstrate that this method significantly improves the accuracy and robustness of SOC estimation for lithium-ion batteries in mining applications. The findings of this paper can provide crucial technical support for intelligent management and maintenance of mining equipment.
  • XU Wanli, HONG Xiaobo, WANG Dongyang, RUAN Dianbo
    Chinese Journal of Power Sources. 2025, 49(4): 772-781. https://doi.org/10.3969/j.issn.1002-087X.2025.04.013
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    Accurate prediction of the state of health (SOH) of lithium-ion batteries is essential to ensure the safe and reliable operation of battery systems. However, the aging of the battery pack is related to the electrochemical reactions within the battery and the inconsistencies between the batteries. Therefore, this paper proposed a SOH prediction method for lithium-ion battery pack based on consistency check. Firstly, multiple features were extracted from the constant current charging voltage curve of the single battery, and based on Pearson correlation method and estimation effect of different feature combinations on battery SOH, the optimal feature set was determined, and the SOH model was established. Secondly, the consistency check method was used on 2 parallel and 20 series battery pack, and different thresholds were set to screen outlier batteries. Finally, the characteristics of each battery in the outlier batteries set were extracted, and combined with the battery SOH model, the SOH of the whole life cycle of the battery pack was predicted. The results show that the root-mean-square error (RMSE) of SOH prediction of battery pack can reach 0.64% with only 20% single battery data, and RMSE decreases by 5.9% compared with no consistency check method, and the relative error of SOH prediction under different aging states is less than 1.5%.
  • ZHANG Wentao, LI Xiaojie, WANG Facheng, WANG Zeyu, ZHANG Yang
    Chinese Journal of Power Sources. 2025, 49(4): 782-793. https://doi.org/10.3969/j.issn.1002-087X.2025.04.014
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    HPPC pulse experiments of 21700 cylindrical lithium-ion batteries were carried out in the experimental platform, and based on the obtained internal resistance data, UDFs were compiled to carry out the transient simulation of battery heat generation. The validity of the model was verified through the battery single discharge experiment. The classical Z-type battery pack structure was constructed, and the discharge simulations of 1 C, 2 C and 3 C were performed for the battery pack of this structure under the environments of 20, 30 and 40 ℃, and the distribution of the temperature field at the end of the discharge was analyzed in depth, so as to summarize the temperature distribution law of the traditional Z-type channel battery pack. According to the simulation results of Z-type battery pack, the position of air inlet and outlet is changed to find out the scheme with less space and better heat dissipation effect. On the basis of this scheme, a variety of schemes were designed for the shape of air inlet and outlet and the position and number of spoilers. Through comparative analysis, the influence of air flow on the temperature field was clarified, and the optimal structure of the battery pack was finally determined. Under the 2 C discharge rate, compared with the original structure, the thermal performance of the battery pack with this structure is significantly improved with the maximum temperature reduced by 4.881 ℃ and the maximum temperature difference reduced by 4.927 ℃, and the maximum temperature difference is controlled within 3 ℃. By optimizing the air-cooled heat dissipation structure, more efficient heat dissipation was achieved in a limited space.
  • YUAN Xinhua, ZHAO Rongchao, ZHA Wenlong, DENG Zhenhua, LI Weihua
    Chinese Journal of Power Sources. 2025, 49(4): 794-805. https://doi.org/10.3969/j.issn.1002-087X.2025.04.015
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    This article studied the effects of adiabatic and immersion cooling environment on thermal runaway of batteries during overcharging at different charging rates (0.5 C, 1 C, 2 C). In the adiabatic overcharge test, the lithium-ion battery was placed in accelerating rate calorimeter; in the immersion cooling test, six batteries were placed in a box containing FS49 hydrofluoroether and the first battery was overcharged. The experiment results show that all adiabatic tests lead to thermal runaway, with the highest surface temperature exceeding 500 ℃, while immersion cooling effectively suppresses the risk of battery thermal runaway and propagation. Overcharging at 0.5 C and 1 C did not cause thermal runaway, and the highest surface temperatures before battery failure were only 26.4 and 30.5 ℃, respectively. Thermal runaway occurred twice in the three repeated tests of 2 C overcharging, with a maximum temperature of 388.8 ℃, but the highest temperatures of other batteries were all below 49 ℃, and no thermal runaway propagation occurred. Therefore, immersion cooling can effectively improve the safety of lithium battery systems.
  • ZHOU Fengyun, LI Panpan, WANG Kangkang, ZHOU Jianjie, SUN Yi, XIANG Hongfa
    Chinese Journal of Power Sources. 2025, 49(4): 806-813. https://doi.org/10.3969/j.issn.1002-087X.2025.04.016
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    This paper investigated the degradation mechanism of a 280 Ah lithium iron phosphate/graphite battery under high-temperature charge/discharge cycling conditions at 45 ℃. The differential voltage curve (dQ/dV) during cycling was analyzed to identify the sources of capacity loss. By disassembling batteries with 100%, 90%, and 60% state-of-health (SOH) lifetimes, the changes in the morphology, structure, and specific capacity of both the positive and negative electrodes were systematically examined. The comprehensive analysis reveals that the reduction in battery capacity is primarily due to the damage to the graphite structure and the loss of active lithium. The decomposition, reformation, and thickening of the solid electrolyte interphase (SEI) layer are the main mechanisms responsible for the depletion of active lithium.
  • LI Shanshou, QIAN Long, YE Wei, HUANG Meichu, XIE Chenlei
    Chinese Journal of Power Sources. 2025, 49(4): 814-823. https://doi.org/10.3969/j.issn.1002-087X.2025.04.017
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    In view of the problems such as slow equalization speed and single equalization path existing in the current equalization circuit topologies and control strategies, a battery pack equalization control circuit topology based on the asymmetric Buck-Boost circuit was proposed. The principles of implementing single-single and multi-asymmetric multi-cell equalization control by the asymmetric Buck-Boost circuit were analyzed. Subsequently, taking the state of charge (SOC) of lithium-ion batteries as the equalization variable, a state- space model of the battery pack was constructed, and the quadratic programming algorithm was used to iteratively optimize the equalization current. Finally, the SOC equalization of the lithium-ion battery pack was achieved by adjusting the duty cycle of the switching transistors. The model of the asymmetric Buck-Boost circuit and the active equalization control strategy was built on the MATLAB/Simulink simulation platform. The simulation verification was carried out for the publicly available lithium-ion battery charge-discharge experimental dataset of the University of Maryland. The results show that the equalization topology of the asymmetric Buck-Boost circuit and the active equalization control strategy model can quickly achieve the SOC equalization of the lithium-ion battery pack. Compared with the traditional topologies and control strategies, the equalization time is shortened by more than 30.9%.
  • ZHU Wentao, LIAO Shuxin, QIU Diankai, PENG Linfa
    Chinese Journal of Power Sources. 2025, 49(4): 824-830. https://doi.org/10.3969/j.issn.1002-087X.2025.04.018
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    Repeated assembly of proton exchange membrane fuel cell (PEMFC) stacks causes assembly force change and output performance degradation. In this study, a cyclic compression experiment was conducted to investigate the effects of cyclic compression on the mechanical property, body resistance and contact resistance of the gas diffusion layer, and a compression rate compensation scheme for different assembly times was proposed. It is found that, with the same compression rate, the pressure and thickness attenuation of the gas diffusion layer mainly occur in the second assembly, with a pressure attenuation of 6.24% and a thickness reduction of 4.64%. In addition, the body resistance and contact resistance of the gas diffusion layer are enhanced by 2.82% and 7.77%, respectively. Hence, an assembly compensation scheme was designed using the satisfaction function to obtain the compression rate interval and the optimal compression rate at different assembly times, which can provide a reference for the optimization of the assembly quality of the PEMFC stack.
  • CHEN Guisheng, LIU Qiang, XU Yangsong
    Chinese Journal of Power Sources. 2025, 49(4): 831-840. https://doi.org/10.3969/j.issn.1002-087X.2025.04.019
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    To address the challenges of insufficient prediction accuracy and limited generalization capability in PEMFC performance prediction, this paper proposed a novel method combining the whale optimization algorithm (WOA), convolutional neural network (CNN), and bidirectional gated recurrent unit (BiGRU) for predicting PEMFC output performance. First, the maximum information coefficient (MIC) was utilized to extract key features that significantly impact PEMFC output performance from large datasets, thereby reducing computational complexity. Next, a CNN-BiGRU model was constructed by integrating CNN's feature extraction ability with BiGRU's advantage in handling bidirectional time-dependent data. The model's hyperparameters were further optimized using WOA to enhance prediction accuracy. Finally, a comparison with traditional prediction models was conducted to demonstrate the superiority of the proposed model. The experimental results show that, when the training set accounts for 60%, the model achieves RMSE values of 0.001 7, 0.001 4, and 0.011 0 on three different PEMFC aging datasets, respectively, confirming the CNN-BiGRU model’s high prediction accuracy and strong generalization ability.
  • FU Xin, HU Guohao, JIANG Shangfeng, SONG Guangji, HAN Yong, XIE An
    Chinese Journal of Power Sources. 2025, 49(4): 841-847. https://doi.org/10.3969/j.issn.1002-087X.2025.04.020
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    Proton exchange membrane fuel cells (PEMFCs) demonstrate immense development potential due to their high efficiency and environmental friendliness. Among them, the flow channel, as one of the indispensable key components of fuel cells, has a crucial impact on gas transport and liquid water removal. Based on the traditional branched straight flow channel, this paper proposed three types of branched wavy flow channels with different radii of R1, R1.5, and R2, and established a three-dimensional, multiphase, and non-isothermal numerical model to comparatively analyze the current density, gas mass transfer, water removal capability, and pressure drop within the flow channel of four different flow channel cells. The research results show that compared with the traditional branched straight flow channel design, the branched wavy flow channel can effectively improve the gas transport, water removal effect, and output performance within the cell. Among them, the R1 design has the best effect. When the output voltage is 0.55 V, the current density increases by 3.52%. However, as the radius decreases, the pressure drop within the flow channel gradually increases.
  • LI Youcai, XIAO Lingyu
    Chinese Journal of Power Sources. 2025, 49(4): 848-851. https://doi.org/10.3969/j.issn.1002-087X.2025.04.021
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    A PEMFC intake system model was built, and the sliding mode controller was loaded into the PEMFC intake system model for simulation research. The results show that the cathode pressure of the PEMFC stack intake system can track the set target value within 0.1 s and reach stability within 10 s, with the steady-state error from the target value being less than 1%. The oxygen excess ratio of the PEMFC stack reaches the target value at 3 s, with a maximum overshoot of 1.6. The net power of the PEMFC stack tracks the target value at 2.7 s, with the maximum net power reaching 53.6 kW and the steady-state error being less than 0.1%, which verifies the accuracy and effectiveness of the sliding mode controller.
  • XU Xiaojing, WANG Xiaohan, CHEN Yanzao, YANG Shaohua, SUN Jie, LI Jilong, DONG Hua
    Chinese Journal of Power Sources. 2025, 49(4): 852-858. https://doi.org/10.3969/j.issn.1002-087X.2025.04.022
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    In this paper, Tin doped iron anode materials for iron nickel secondary batteries were prepared by the sol gel method using FeC2O4·2H2O as the iron source, SnO2 as the tin source, citric acid as the carbon source and reducing agent. The influence of different citric acid contents on anode materials was explored, and the effects of two sulfide additives, NiS and FeS, on the performance of the synthesized anode were investigated. XRD, SEM, CV and EIS were used to characterize the structure, morphology, and electrochemical properties of the synthesized materials. The results show that high temperature sintering of citric acid into carbon provides the main carbon source for the negative electrode material, and when the ratio of metal ions to citric acid was 1∶1.5, the iron specific capacity prepared reaches 523 mAh/g. The addition of appropriate proportions of sulfides can enhance the specific capacity of anode materials. Among them, the anode material with 5% FeS added has a discharge specific capacity of 582 mAh/g, the highest discharge specific capacity, and good cycling stability.
  • LI Min, WU Tao, ZHAN Xianglian, CHEN Longxia, MENG Xiuxia
    Chinese Journal of Power Sources. 2025, 49(4): 859-864. https://doi.org/10.3969/j.issn.1002-087X.2025.04.023
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    Based on the humic acid formula, the effect of adding organic expansion agents such as tannin extract, sodium lignosulfonate, and ethanol to treat humic acid on the performance of lead-acid power batteries was studied. Through differential thermal analysis, SEM observation, low-temperature capacity, and high-temperature resistance performance, it is found that oak extract, ethanol treated humic acid, and sodium lignosulfonate can improve the low-temperature capacity of batteries. However, the thermal stability of oak extract is relatively poor. Therefore, ethanol treated humic acid and sodium lignosulfonate are preferred for further content optimization. The content optimization experiment shows that the combination of humic acid and sodium lignosulfonate treated with ethanol, as well as the further increase in the amount of sodium lignosulfonate added, contribute to the further enhancement of low-temperature capacity. However, as the amount of sodium lignosulfonate added increases, the charging acceptance capacity of the battery decreases. When it exceeds a certain amount, there is a risk of premature termination of the battery life.
  • CAO Yu, XU Guijing, WANG Dongdong, WANG Feng, JIANG Yunshan, DENG Liang, ZHAO Lei, WANG Zhenbo
    Chinese Journal of Power Sources. 2025, 49(4): 865-868. https://doi.org/10.3969/j.issn.1002-087X.2025.04.024
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    The battery stack is the core component of the thermal battery. Its manufacturing process consists of two key processes: electrode pressing and multi-electrode assembly. When large-sized thin electrodes are pressed automatically, there is a deviation between their physical properties and the requirement of the automation equipment. The formability of the positive electrode material is insufficient, which affects the forming rate of the positive electrode. This paper studied the problem of organic carbon-coated positive electrode materials. By coating the surface of the positive electrode powder particles with a porous and rough carbon layer, the forming rate of the positive electrode material was improved, which provides a method for pressing large-sized thin positive electrode sheets.
  • Research and design: Physical power sources
  • GAO Shengqiang, ZHANG Lin, WANG Haipeng, SONG Yu, YAN Hao, LIU Zining, ZHOU Weiwei, BU Shuaiyu
    Chinese Journal of Power Sources. 2025, 49(4): 869-882. https://doi.org/10.3969/j.issn.1002-087X.2025.04.025
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    To significantly enhance the prediction accuracy of the output power of photovoltaic (PV) power station, this paper developed an intelligent prediction model for PV output through incorporating CCM, IGRA, PSO and BiLSTM into a general framework. Firstly, the convergent cross mapping (CCM) algorithm was employed to extract key meteorological elements affecting PV output, where they are considered as major evaluation criteria of similar day selection and critical input variables of subsequently established prediction model; secondly, an improved grey relational analysis method (IGRA) based on entropy weight method was utilized to select historical similar days that closely match meteorological characteristics of the day to be predicted. And then, selecting the critical weather parameters and PV power generation sequence of similar days as the training samples, the particle swarm optimization (PSO) algorithm was used to determine optimal hyperparameters combination for the bidirectional long short-term memory (Bi-LSTM) network. A high-precision PV output prediction model based on CCM-IGRA-PSO-BiLSTM for the predicted days was established. Three criteria, including mean absolute error (MAE), mean absolute percentage error (MAPE) and root mean square error(RMSE), were selected as the evaluation metrics for model performance. The obtained results indicate that, taking the sunny weather in spring as an example, the proposed combined model achieved MAPE, MAE and RMSE of 0.38%, 0.06 and 0.07 MW, respectively, all of which surpass those of several baseline models. This way provides scientific guidance and support for the station to formulate reasonable production plan and electricity market participation strategy.
  • Research and design: Systemtechnology
  • LIU Shufeng, CHEN Maosheng, ZOU Jiwei, SHAN Feng, SONG Tao, SUN Zhengyang
    Chinese Journal of Power Sources. 2025, 49(4): 883-886. https://doi.org/10.3969/j.issn.1002-087X.2025.04.026
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    In view of the current situation of long construction cycle and high cost of domestic commercial satellite constellation, the batch production of satellite power subsystem was explored based on the batch production of Jilin-1GF03 satellites. Based on the batch design concept of processing, assembly and testing for satellite, the batch design of solar arrays, lithium-ion battery pack and power controller was carried out respectively. The power subsystem has the characteristics of low cost, low weight and low power consumption. The power subsystems of 64 satellites all operate stably and reliably in orbit, and the indicators are consistent. The batch production experience of this type of spaceborne equipment can provide some reference for the construction of large-scale domestic commercial satellite constellations.