CHEN Wentao, WEI Zhen, LI Qian, LIU Shiqiang
With the accelerated global transition toward a renewable-dominated energy system, electrochemical energy storage has become a critical infrastructure supporting the flexibility, stability, and high-quality operation of new-type power systems.Lithium-ion batteries, represented by LiFePO4 and ternary chemistries, dominate large-scale energy storage applications due to their high energy density, mature industrial foundation, and rapid cost reduction. However, a series of large-scale energy storage fires and explosions have exposed significant weaknesses in thermal management, system integration, operational control, and safety standards. This review systematically analyzed the multi-level coupling mechanism of thermal runaway in energy-storage lithium-ion batteries-from materials, electrodes, cells, and modules to system-level and summarized key triggers such as internal short circuits, overcharge abuse, cooling failure, cell inconsistency, and insufficient environmental tolerance. Typical accidents were examined to reveal chain-reaction propagation pathways. Furthermore, a comparative assessment of the safety standards in China, the United States, and Europe identifies that China has established relatively comprehensive cell-level testing requirements, whereas system-level thermal propagation evaluation, scenario-based environmental adaptability assessment, and lifecycle-oriented safety governance remain to be strengthened. Based on these findings, this paper proposed several directions for improving storage-system safety, including system-level thermal propagation and full-scale fire tests, multi-climate adaptability standards, AI- and digital-twin-enabled proactive safety management, improved operation-and-maintenance and decommissioning protocols, and enhanced international standard coordination. These measures are expected to support the high-safety and high-quality development of China’s energy storage industry.