LI Binqi, ZHOU Fen, ZHANG Hui, PAN Mu
The electrochemical corrosion problem of cathodic carbon carriers in proton exchange membrane fuel cells (PEMFCs) severely restricts their lifetimes, and the oxidation state of platinum (Pt) catalysts is closely related to the carbon corrosion behavior. In this study, the carbon corrosion mechanisms of Pt/C electrodes and pure C electrodes driven by different potentials were systematically investigated by real-time monitoring of CO₂ release characteristics by non-dispersive infrared spectroscopy (NDIR), combined with triangular-wave cycling potential and constant potential tests. The carbon corrosion rate of the Pt/C electrode under the triangular wave potential cycling condition has five characteristic peaks, from which seven key characteristic potentials are identified: the forward cycling characteristic potentials TP1, TP2, TP3, and TP4 are 0.20, 0.55, 0.70, and 1.00 V, respectively, and the reverse cycling characteristic potentials TP5, TP6, and TP7 are 1.00, 0.75, and 0.30 V, respectively. Under constant potential operation, unlike the carbon corrosion rate of pure C electrode which increases monotonically with the rise of constant potential, the carbon carrier corrosion rate of Pt/C electrode rises and falls with the rise of constant potential, and the corrosion rate values are in the order of 1.00 V > (0.50 V≈ 0.70 V) > 0.90 V > 0.80 V, which suggests that the fuel cell should be operated to avoid higher and relatively lower operating potentials. Combined with the analysis of the chemical state of the surface of pure carbon electrode and Pt electrode at different potentials, the results show that the catalytic activity of Pt in Pt0 state is the highest for carbon carrier corrosion, and with the rise of potential the oxidation degree of Pt is deepened, and its catalytic activity for carbon carrier corrosion is also gradually weakened. Operating at 1.00 V or above for a long time, the catalytic effect of the stable oxides formed on the surface of Pt on carbon corrosion is negligible