中文核心期刊
中国科技核心期刊
中国化学与物理电源行业协会会刊
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20 August 2021, Volume 45 Issue 8
    

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    Research and design
  • SUN Jing, KOU Liang, ZHANG Cheng, ZHANG Chao, WANG Jifeng
    Chinese Journal of Power Sources. 2021, 45(8): 965-968. https://doi.org/10.3969/j.issn.1002-087X.2021.08.001
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    High nickel layered oxide cathodes show substantial potential for next generation lithium ion batteries due to high capacity and lower cost. However, they are restricted by rapid capacity decay and poor thermal stability, which hampers large-scale applications. In this paper, we propose Mg2+ or/and W6+ doping in the Ni0.88Co0.09Mn0.03(OH)2 precursor. The corresponding cathode materials are synthesized by high temperature solid state method. We research the effects of different doping elements on the precursor and cathode materials. The results show that the Li0.991Mg0.009Ni0.879Co0.090Mn0.030W0.001O2 cathode material which Mg2+ and W6+ co-doping in precursor has excellent comprehensive performance. It delivers initial reversible capacity is 217 mAh/g at 0.1 C, and capacity retention rate is 90.82% after 100 cycles at 1 C. It also shows excellent rate performance that the discharge capacity is approximately 184 mAh/g at 5 C. In addition, the Mg2+ and W6+ co-doping significantly elevates the exothermic peak temperature to 221.8 ℃, indicating the thermal stability is improved. This study proves that comprehensive performance of co-doping cathode material is optimal, which provides a feasible strategy for the development of a safer and higher energy density lithium ion battery cathode material.
  • SU Xiang
    Chinese Journal of Power Sources. 2021, 45(8): 969-971. https://doi.org/10.3969/j.issn.1002-087X.2021.08.002
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    With the promotion of new energy vehicles, the defect of low charge and discharge rate of lithium ion batteries is gradually revealed. Commercial battery materials cannot meet people's needs for fast charging. This seriously hinders the promotion and development of electric vehicles. In this article, the author takes lithium nickel manganese oxide as the research object, using polyethylene glycol 200, polyethylene glycol 1000, and polyethylene glycol 4000 as surfactants, lithium nickel manganate cathode materials with different structures were prepared by hydrothermal method. The results show that the particle size of the material prepared with polyethylene glycol 4000 is smaller, the specific discharge capacity at 0.5 C rate is 139 mAh/g. And its rate charge and discharge performance is significantly better than other materials.
  • LIANG Libo, YANG Shenglong, JIANG Ying, LAI Feiyan, ZHANG Xiaohui
    Chinese Journal of Power Sources. 2021, 45(8): 972-975. https://doi.org/10.3969/j.issn.1002-087X.2021.08.003
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    Waste graphite from spent lithium ion batteries (LIBs) was treated by concentrated sulfuric acid to leach metals and impurities, the obtain sulfuric acid-treated graphite (ALG) was recombinated with iron source to prepare high-performance Fe3O4@Fe/ALG composite materials as anode material for LIBs. Scanning electron microscope (SEM) and Transmission electron microscopy (TEM) images show that nanoscale Fe3O4 and metallic Fe particles are uniformly dispersed in graphite nanosheets. Nano-Fe particles improve conductivity of the composite and make an catalytic effect on activity of the regenerated graphite. X-ray photoelectron spectroscopy (XPS) detects the presence of carboxyl (C(O)O) groups in the Fe3O4@Fe/ALG composites, which can help prevent the co-intercalation of solvent molecules and improve wettability of the material to electrolyte and then decrease interfacial impedance. The groups transforms into carboxylate and-Oli groups in the first lithium intercalation process and forms a stable solid electrolyte membrane. The electrochemical test results show that the specific discharge capacities of the Fe3O4@Fe/ALG composite remains 590 mAh/g after 100 cycles at 0.1 C and 497.6 mAh/g after 300 cycles at 0.5 C, suggesting superior capacity and cycling performance. This method offers a new strategy to recycle waste graphite anode in spent LIBs. In addition, the simple technology and good electrochemical performances of the Fe3O4-based composite are favorable to production in large scale as well as practical application.
  • SHI Jintao, ZHEN Huijuan, MA Yuzhao, ZHOU Jiang
    Chinese Journal of Power Sources. 2021, 45(8): 976-978. https://doi.org/10.3969/j.issn.1002-087X.2021.08.004
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    Nickel-rich cathodes vs silicon/graphite anodes lithium ion cell is an important direction to improve energy density. The purpose of this paper is to investigate the cycle performance of batteries with different silicon content in negative electrode. EIS was used to study the state of health of the battery and identify the main physical and chemical processes during the lithiation and delithiation of the electrode. EIS and DRT were used to study the impedance characteristics of nickel-rich vs silicon/graphite battery during cycle aging. It was found that the lithium ion diffusion process in electrolyte was the predominant impedance when SOC is 50%.
  • LI Shuang, ZHANG Shuguo, DU Chenshu
    Chinese Journal of Power Sources. 2021, 45(8): 979-982. https://doi.org/10.3969/j.issn.1002-087X.2021.08.005
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    The anode and cathode materials optimized by reducing particle size and carbon coating respectively, and the morphology of lithium cobalt oxide and graphite were characterized by SEM. Four kinds of battery samples were prepared by controlling variables. Their electrochemical impedance, charge-discharge curve and capacity differential curve at low temperature, as well as lithium evolution were analyzed. The results show that appropriately reducing the particle size of lithium cobalt oxide and carbon coated modified graphite are two ways to optimize the anode and cathode materials, and the combination of the two can improve the low-temperature performance.The optimized cathode material can improve the low temperature discharge performance obviously, and the optimized anode material can improve the low temperature charging performance obviously. The mismatching of material activity between positive and negative poles or the mismatching of material and using conditions may cause performance defects.
  • XU Liyang, CHEN Meng, CHEN Long, XIE Yuhu, LI Kai
    Chinese Journal of Power Sources. 2021, 45(8): 983-985. https://doi.org/10.3969/j.issn.1002-087X.2021.08.006
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    The effects of different separators on the performance of lithium ion batteries were studied by using LiFePO4/graphite as anode and cathode materials. The results show that the porosity of the separator is negatively correlated with the air permeability, and the thickness of the separator is positively correlated with the air permeability. With the increase of separator porosity, the ACR/DCR of the battery will decrease, the self discharge will increase, and the discharge performance at -20 ℃ will become worse. With the thickness of the separator becoming thicker, the ACR/DCR of the battery will become smaller, the self discharge will be smaller, and the discharge performance at -20 ℃ will be improved. In addition, at the same thickness, the ACR/DCR of dry separator battery are smaller, the self discharge is slightly larger, and the discharge performance at -20 ℃ is slightly poor.
  • ZHENG Tao, LI Yang, SANG Lin, LIU Xingjiang
    Chinese Journal of Power Sources. 2021, 45(8): 986-988. https://doi.org/10.3969/j.issn.1002-087X.2021.08.007
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    Three dimensional network flame retardant silicon gel electrolyte has been successfully synthesized via in-situ polymerization process. The electrical properties were characterized by electrochemical impedance spectra, rate dischargeability and cycle performance test. The results showed that three-dimensional network flame retardant silicon gel electrolyte has a certain mechanical strength, and has a certain protective effect to positive and negative, the ionic conductivity was greater than 5×10-4 S/cm at room temperature. The number of the gel battery cycle life could be reached 500 times with 0.33 C.
  • ZHAO Xingyun, AI Jinjin, WANG Jingjing, LAI Chunyan
    Chinese Journal of Power Sources. 2021, 45(8): 989-992. https://doi.org/10.3969/j.issn.1002-087X.2021.08.008
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    In order to improve the electrochemical properties of the tin oxide as anode material for lithium ion battery, SnO2 coated with chemical doping polyaniline (SnO2@PANI) composite was synthesized by chemical oxidation. The composite materials were analyzed by powder X-ray diffraction (XRD), scanning electron microscope (SEM), infrared absorption spectrum (FTIR), specific surface area analysis (BET), thermal analysis and electrochemical testing. The results show that the surface of the tin dioxide was successfully coated by polyaniline, and the crystal structure of tin oxide was not affected. The electrochemical testing shows that the cycling stability of the anode electrode material was gradually improved with the coating of polyaniline, especially that the SnO2@PANI composites with 23% PANI shows the best cycle stability. At a current of 100 mA/g, it still remains 594 mAh/g reversible capacity after 100 cycles. This result shows that the chemical doping polyaniline could significantly improve the electrochemical performance of tin dioxide.
  • LIU Ping, QU Xinbo, LI Jialin, YU Liwei
    Chinese Journal of Power Sources. 2021, 45(8): 993-995. https://doi.org/10.3969/j.issn.1002-087X.2021.08.009
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    It is found in the experiment that the expansive force of large capacity lithium iron phosphate battery presents a nonlinear change trend during the charging and discharging process. In BOL, the maximum value of expansive force appears at 100% SOC, but there is another peak value near 30% SOC. This phenomenon is related to the lithium ion embedded in the negative electrode. As the number of cycles increases, we find that the increase of expansion force of 30% SOC is gradually greater than that of 100% SOC, which becomes the peak pressure. When the peak pressure of 30% SOC exceeds 100% SOC, the battery capacity will show accelerated decay.
  • MEI Jian, QIU Lvchao, HUI Yang, ZHAO Zhoufeng, ZOU Junwen
    Chinese Journal of Power Sources. 2021, 45(8): 996-1000. https://doi.org/10.3969/j.issn.1002-087X.2021.08.010
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    With a retired lithium iron phosphate pouch batteries as an object, the discharge capacity, internal resistance and self-discharge were analyzed, the AC impedance characteristics under different charged state were tested, the charging and discharging characteristics of the different rate and different temperature conditions were researched, the cycle life and calendar life were tested and the security performance of the battery under the abuse condition were researched. The results show that the capacity of the battery in about 85% of the rated capacity, the majority of battery internal resistance between 2.4~3.4 mΩ, after 28 days standing, the capacity retention ratio is above 97%, with the decrease of the SOC, the charge transfer impedance begins to increase gradually. At 25 ℃, it has a good cycle performance, but at 45 ℃, the cycle performance is significantly reduced. At room temperature, it has a good calendar life. When the temperature is 0 ℃ or above, the battery has good rated charging-discharge characteristics. The battery can pass many safety tests and show good safety performance.
  • LI Yue, LI Tianqi, QIN Jianhua, JIN Tai, PAN Chongchao
    Chinese Journal of Power Sources. 2021, 45(8): 1001-1004. https://doi.org/10.3969/j.issn.1002-087X.2021.08.011
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    In this paper, a two-dimensional axisymmetric electrochemical-thermal coupling model is established using the multiphysics coupling software COMSOL-Multiphisics. The heat generation in the electrode area and diaphragm area of the 18650 lithium iron phosphate battery under different discharge rates is explored. According to the heat accumulation in different regions, the influence of the increase of the discharge rate on different types of heat generation such as reaction heat, ohmic heat and polarization heat is further analyzed. The results show that with the increase of the discharge rate, the heat generation area is mainly the positive electrode and the diaphragm heat generation, and the heat generation type is mainly ohmic heat. The ohmic heat accounts for 72.43% of the total heat generation during 3 C discharge, and the reaction heat and polarization heat is relatively small.
  • SONG Yajuan, SHEN Jie, XU Zhen, QIANG Liwei, ZHANG Manqin
    Chinese Journal of Power Sources. 2021, 45(8): 1005-1007. https://doi.org/10.3969/j.issn.1002-087X.2021.08.012
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    In view of the risk of thermal runaway in the lithium ion battery for low speed electric vehicle, orthogonal test is used in this paper, the main factors that causing the risk of thermal runaway, such as different temperature, charging current, discharging current and charge state are studied. The primary and secondary factors that causing the thermal runaway of the battery during charging and discharging are obtained. The suggestions and technical support for reducing the risk of thermal runaway in low-speed electric vehicles and battery manufacturing enterprises are put forward.
  • LI Chen, JIANG Bing, XIA Weidong, XU Honghua, MA Hongzhong
    Chinese Journal of Power Sources. 2021, 45(8): 1008-1011. https://doi.org/10.3969/j.issn.1002-087X.2021.08.013
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    The short circuit of lithium ion battery is the main cause of thermal runaway of lithium ion battery. In particular, in the scenario of cascade utilization, the batteries connected in series are more likely to get of the short circuit due to the inconsistency which adds the risk of thermal runaway. When one battery is under short circuit, its voltage can decline obviously due to the release in energy, while voltages of other batteries will not, therefore the decline in battery voltage can be used to identify short circuit. Nevertheless, the feature of the decline in voltage may be covered by inconsistency. Thus this paper uses zero-mean and correlation coefficient to present the feature of decline in voltage, on the basis of the elimination of inconsistency, so as to identify short circuit reliably. The effectiveness of the proposed method is verified by the typical working condition of FUDS.
  • MENG Xianling, YANG Zhong, SU Xiaoqian, YANG Fangning, MU Hao
    Chinese Journal of Power Sources. 2021, 45(8): 1012-1015. https://doi.org/10.3969/j.issn.1002-087X.2021.08.014
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    The lithium carbon fluoride-manganese dioxide battery using carbon fluoride and manganese dioxide composite materials as the positive electrode not only retains the high specific energy characteristics of carbon fluoride materials, but also has the advantages of good rate performance of manganese dioxide. Like other primary batteries, storage performance is an important indicator that affects the operational reliability of lithium carbon fluoride-manganese dioxide batteries. The influence of positive electrode drying temperature, pre-discharge process, binder and storage temperature on the storage life of lithium fluorocarbon-manganese dioxide battery was studied. The results show that when the drying temperature is 150~180 ℃, the swelling problem of the battery is significantly inhibited, which is beneficial to improve the long-term storage of the battery. When the ratio of pre-discharge capacity is over 3%, the swelling problem of the battery can be inhibited, and it has nothing to do with the discharge current within the scope of the test. The binder N1 can affect the integrity of the positive electrode and the reliability of the battery storage performance. As the storage temperature increases, the self-discharge reaction rate of the battery accelerates, and the capacity loss rate in the early stage of high-temperature storage is greater. With the formation of the surface passivation film, the surface state of the positive and negative electrodes tends to be stable, and the battery self-discharge reaction rate also slows down accordingly.
  • MA Xiaoyan, CHEN Anguo
    Chinese Journal of Power Sources. 2021, 45(8): 1016-1017. https://doi.org/10.3969/j.issn.1002-087X.2021.08.015
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    In this paper, activated carbon/lithium titanate@activated carbon lithium ion capacitors(LIC) was prepared by coated, rolled and winded with active carbon as cathode material and lithium titanate(LTO) doped with different proportion of activated carbon (AC) as anode material. In this paper, a variety of LTO@AC materials were prepared by doped different proportions of AC, the electrode piece was then obtained by the LTO@AC. A series of electrochemical performance tests were carried out for the LIC assembled by electrode piece LTO@AC. The influence of electrode on specific energy and specific power of LIC was researched. The results showed that: doped AC into LTO could not significantly reduce the specific energy of LIC, but could significantly improve the specific power of LIC; when the mass ratio of LTO to AC is 1:1, LIC achieve relatively optimal electrochemical performance, with energy density of 46.06 Wh/kg and power density of 6.5 kW/kg.
  • LU Jiabin, SHEN Xinming, CHEN Ming, ZHU Fengjuan, ZHANG Junliang
    Chinese Journal of Power Sources. 2021, 45(8): 1018-1022. https://doi.org/10.3969/j.issn.1002-087X.2021.08.016
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    By combining numerical simulation and experimental measurements, the effects of cathode humidity(40%,70% and 100%) on PEMFC performance was studied at different current density. At low current densities, cathode humidity has no significant effects on PEMFC performance; at middle current densities, the PEMFC with 70% cathode humidity showed the best performance; at high current densities, the PEMFC at 40% cathode humidity performed best. By analyzing the CFD results, it is found that increasing cathode humidity would improve membrane water content and improve PEMFC performance; when the membrane water content is saturated, increasing humidity would increase liquid water saturation in GDL, which decreases PEMFC performance. As the current density increasing, it is suggested to decrease cathode humidity in order to have the best cell performance.
  • MIAO Yuhang, XING Lu, CHENG Wenjun, NI Haoyi, TU Zhengkai
    Chinese Journal of Power Sources. 2021, 45(8): 1023-1026. https://doi.org/10.3969/j.issn.1002-087X.2021.08.017
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    The operation characteristics of air-cooled PEMFC at different altitudes were studied in detail. The effects of operating pressure, inlet temperature and stoichiometry on the performance of PEMFC were analyzed. The results show that the performance of PEMFC decreases by 10% at the same inlet temperature when the altitude increases from 0 m to 4000 m. The output power decreases by 25.5% when the inlet temperature decreases simultaneously with the increase of altitude. Increasing the cathode stoichiometry can increase the concentration of reactants, thus it can improve the performance and reduce the internal temperature difference of PEMFC.
  • ZHANG Long, ZHAO Xiran, FU Yuchen
    Chinese Journal of Power Sources. 2021, 45(8): 1027-1030. https://doi.org/10.3969/j.issn.1002-087X.2021.08.018
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    The effects of high pressure treatment on the phase structure, microstructure and electrochemical properties of La0.68Mg0.32Ni3.2 hydrogen storage alloy were studied by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical workstation. The results show that as-cast La0.68Mg0.32Ni3.2 hydrogen storage alloy is mainly composed of (La, Mg)Ni and (La, Mg) 2Ni7 phases and contains a small amount of (La, Mg)5Ni19, LaNi5 and (La, Mg)Ni4 phases; after high pressure treatment, the content of (La, Mg)Ni3 phase increases while that of (La, Mg)2Ni7 phase decreases in La0.68Mg0.32Ni3.2 hydrogen storage alloys. The higher the pressure, the higher the content of (La, Mg) Ni3 phase and the less the content of (La, Mg)2Ni7 phase. The maximum discharge capacity of La0.68Mg0.32Ni3.2 hydrogen storage alloy electrodes treated by 1 GPa is obviously higher than that of the alloy electrodes treated by 3 GPa and 5 GPa pressure. The capacity retention rate of the alloy electrode after 100 cycles(S100) at 1 GPa pressure is the highest, while the S100 of alloy electrode under 3 GPa and 5 GPa pressure is even lower than that of as cast alloy electrode. The electrocatalytic activity of La0.68Mg0.32Ni3.2 hydrogen storage alloy electrodes after high pressure treatment is obviously improved, and the dynamic performance of the electrodes is better than that of as-cast alloy electrodes. The hydrogen diffusion rate of as-treated La0.68Mg0.32Ni3.2 hydrogen storage alloy electrodes decreases compared with as-cast hydrogen storage alloy electrodes, and the high rate discharge performance of La0.68Mg0.32Ni3.2 hydrogen storage alloy electrode is related to hydrogen diffusion coefficient.
  • YAO Yuanxin, YIN Xingyue, ZHANG Qiming, YU Hui
    Chinese Journal of Power Sources. 2021, 45(8): 1031-1033. https://doi.org/10.3969/j.issn.1002-087X.2021.08.019
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    In this paper, by analyzing the characteristics of low intensity low temperature test environment, the solar simulator and the temperature control platform are transformed to meet the requirements of low intensity low temperature test. In addition, the test environment is verified, and the result shows that the environmental conditions of the test platform meet the test requirements. Finally, the low intensity low temperature test of the sample battery is completed.
  • LI Jing, WANG Guimei, WANG Yuxiao, LIU Miao, XU Zhiwei
    Chinese Journal of Power Sources. 2021, 45(8): 1034-1035. https://doi.org/10.3969/j.issn.1002-087X.2021.08.020
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    The effect of PECVD process on the PID of polysilicon cell is studied. The experimental results show that the anti PID performance of multilayer film is better than that of single-layer film. The anti PID performance can be significantly improved by removing the pre deposition step. When the film thickness is fixed, the higher the refractive index, especially the contact silicon sublayer, the better the anti PID performance; when the refractive index is constant, the higher the film thickness, especially the contact silicon wafer sublayer, the better the anti PID performance. By optimizing the process parameters of poly silicon cell tube PECVD, the anti PID performance of the module can be improved.
  • LEI Maojie, XU Tanqi, MENG Fanying
    Chinese Journal of Power Sources. 2021, 45(8): 1036-1039. https://doi.org/10.3969/j.issn.1002-087X.2021.08.021
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    The use of maximum power point tracking (MPPT) technology has greatly improved the conversion efficiency of photovoltaic modules. In the case of obstruction, the photovoltaic array will show a multi-peak output curve. The traditional MPPT method is easy to fall into the local maximum power point and cannot track the global maximum power point. Among the global algorithms, ordinary particle swarm algorithms have some problems such as slow convergence speed, premature populations, and sensitivity to initial conditions. To solve this problem, this paper proposes a new algorithm based on adaptive particle swarm optimization (APSO) MPPT control strategy. By introducing adaptive parameter algorithm and random particles to speed up the convergence speed of the particle swarm, it not only solves the problem that the INC method cannot find the global maximum point and the search speed is slow, but also solves the problem of the large randomness of the PSO algorithm and the slow convergence speed and the problem of greater volatility. The photovoltaic system model is built in Matlab/Simulink, and the proposed algorithm is simulated under the conditions of fixed irradiance and dynamic irradiance. The results show that: compared with the traditional method and traditional particle swarm optimization algorithm, the MPPT control strategy proposed in this paper can greatly improve the tracking accuracy, tracking speed and response speed, and can improve the conversion efficiency of photovoltaic modules.
  • GUO Kunli, LIU Luyu, CAI Weizheng
    Chinese Journal of Power Sources. 2021, 45(8): 1040-1043. https://doi.org/10.3969/j.issn.1002-087X.2021.08.022
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    In the practical application process of photovoltaic array, local shading occurs, and the output characteristic P-U curve presents multi peak situation. In this paper, a hybrid algorithm is proposed, which uses a "two-step" strategy to search the global maximum power point. Firstly, the particle swarm optimization (PSO) and genetic algorithm (GA) are used to search the maximum power point through a small number of iterations. Then switch to the fuzzy control method to search the maximum power point and stabilize. This hybrid algorithm makes up for the shortcomings of single algorithm and improves the speed and accuracy of the system. Through the complementary advantages and disadvantages of particle swarm optimization and genetic algorithm, it can avoid falling into the local optimal value and reduce the convergence time. The fuzzy control method can make the system stable at the maximum power point and avoid the energy loss caused by oscillation. Finally, the Simulink simulation results show that the proposed hybrid algorithm has better tracking performance and response speed.
  • FAN Jianqiang, SUN Ruijuan, LI Hongbin
    Chinese Journal of Power Sources. 2021, 45(8): 1044-1047. https://doi.org/10.3969/j.issn.1002-087X.2021.08.023
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    In order to improve the tracking control effect of solar cell maximum power point, this paper studies the maximum power point tracking control (MPPT) of solar cell. Firstly, the characteristics of solar cells are studied, and then MPPT control is analyzed. The combination of particle swarm optimization algorithm and conductance addition method is selected as the control strategy in this paper. On this basis, Motorola MCU is designed to realize the tracking control of the maximum power of solar cells. The simulation results show that: in the tracking control of the maximum power point of the solar cell, the response of this method is fast and timely, the output power of the system is stable, and the maximum power tracking control of the solar cell is effectively realized, which has a certain application prospect.
  • LI Bao, SUN Shumin, WANG Shibai, CHENG Yan, CHENG Wen
    Chinese Journal of Power Sources. 2021, 45(8): 1048-1051. https://doi.org/10.3969/j.issn.1002-087X.2021.08.024
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    In order to get a good understanding of the impact of distributed photovoltaic grid connection on the power system, a prediction method for regional distributed photovoltaic output is proposed considering spatial correlation. Firstly, the correlation analysis between the centralized power station in the same area and all distributed power stations in the area is performed, and all distributed power stations whose correlation coefficient with the respective centralized power station reaches the threshold value are equivalent to virtual centralized power stations. Then the fuzzy neural network (ANFIS) prediction method is used to obtain the target date force of the centralized power station. Meanwhile, the target date power of the virtual centralized power station is obtained from the target date power of the centralized power station through curve fitting. All the virtual centralized power plants in the area are summed to get the output of distributed power plants in the area. Finally, taking a photovoltaic power plant in a region in northern China as an example, the effectiveness of this method is verified. It has certain practical significance for the construction and grid connection of photovoltaic power stations in the future.
  • LI Guangming, ZHENG Lina, FAN Wei, JI Chang, LIU Long
    Chinese Journal of Power Sources. 2021, 45(8): 1052-1054. https://doi.org/10.3969/j.issn.1002-087X.2021.08.025
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    To accurately grasp the output of the power station in the future, taking a large photovoltaic power station in Yunnan as an example, the factors affecting the output of the photovoltaic power station were analyzed. A BP neural network output prediction model was established, which was based on the meteorological data measured by the power station and the small and medium scale. The numerical weather forecast data trains the prediction model and predicts the power output of the 15 min resolution of the power station at 8:00~18:30 on January 1, 2020. The results show that the actual meteorological data is used as training. The prediction effect of the sample is better. The prediction indexes of MAE, RMSE, R and Q are 9.03%, 12.33%, 0.980 and 95.24%.
  • WANG Shenghui, WANG Zhengyu, CHEN Shu, LI Xiaoxiao, WANG Zhixi
    Chinese Journal of Power Sources. 2021, 45(8): 1055-1060. https://doi.org/10.3969/j.issn.1002-087X.2021.08.026
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    The control strategy of high efficiency optical storage power generation system can not only improve the system efficiency, but also calm the fluctuation of solar power output power and improve the power quality of photovoltaic power generation. This paper presents an optimal control strategy for optical storage power generation system based on power prediction. The photovoltaic power prediction algorithm is optimized. The artificial fish swarm algorithm based on following behavior is combined with BP neural network, and the weight and threshold of the neural network are optimized by using the artificial fish swarm algorithm based on following behavior. The optimized photovoltaic power prediction method is used to predict the PV output power curve in the next period and judge the fluctuation. The judgment result is taken as one of the main factors affecting the operation of the strategy, and the corresponding working mode is designed according to different situations. Through Matlab modeling and simulation, it is proved that the optimized control strategy can more effectively suppress the output fluctuation of photovoltaic.
  • ZHANG Guoyu, WANG Honghua, ZHAO Huiwen
    Chinese Journal of Power Sources. 2021, 45(8): 1061-1065. https://doi.org/10.3969/j.issn.1002-087X.2021.08.027
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    Accurately establishing the mathematical model of PV modules is the basis of theoretical research of PV power generation systems. Aiming at the problems that low accuracy of the single-diode model and difficult solution of the two-diode model because of its too many parameters, without any approximation, a hybrid method based on adaptive chaotic particle swarm optimization (ACPSO) was presented, which was based on the two-diode model and took into account both model accuracy and algorithm complexity. In this method, the parameters of the model can be obtained by using only six parameters at the standard test condition, namely the short-circuit current, the open-circuit voltage, the voltage and current at maximum power point, the temperature coefficients for open-circuit voltage and short-circuit current. The effectiveness and accuracy of the proposed method were verified by PV characteristic simulation for different types of PV modules at different conditions.
  • ZHOU Weiqi, ZHANG Junbo, LUO Ding, WANG Ruochen
    Chinese Journal of Power Sources. 2021, 45(8): 1066-1069. https://doi.org/10.3969/j.issn.1002-087X.2021.08.028
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    In view of the low power generation efficiency of the current automobile tail temperature difference, the thermoelectric power generation model is obtained by building a thermoelectric power generation experimental platform to verify the feasibility of the maximum power point tracking (MPPT) algorithm. By building a test platform, analyzing the operating characteristics of the open circuit voltage and temperature difference of the thermoelectric sheet, and drawing the load characteristic curve, combined with the improved bipartite gradient MPPT control algorithm, to improve the recovery efficiency of thermoelectric power generation. The Matlab/Simulink simulation results show that: compared with the traditional open circuit voltage method (OCV) and perturbation and observation method (P&O), the MPPT algorithm proposed in this paper achieves a greater improvement in tracking accuracy and speed, and provides certain guidance for subsequent thermoelectric power generation experiments and algorithm research.
  • JIA Houkang, DUAN Yanpu, NI Shuang
    Chinese Journal of Power Sources. 2021, 45(8): 1070-1072. https://doi.org/10.3969/j.issn.1002-087X.2021.08.029
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    The battery need different performance tests to carry out in the stages of manufacture, installation and maintenance, in order to obtain information such as capacity, internal resistance, life and so on. With the application of the third generation nuclear power technology, large-capacity batteries are becoming more and more popular. The discharge current of these large-capacity batteries is as high as 1 500 A and the voltage is 220 V(DC). At present, the domestic battery testing instruments can’t meet the test requirements. This paper will study the working characteristics of the high-power battery tester, explore the development ways, and realize the programmable, combined use and battery monomer monitoring functions of the tester.
  • JIN Biao, ZOU Wuyuan, LIU Fangfang, AN Zhiwen
    Chinese Journal of Power Sources. 2021, 45(8): 1073-1076. https://doi.org/10.3969/j.issn.1002-087X.2021.08.030
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    In order to make minimize the mass of a designed hybrid battery thermal management system(BTMS), and meet the requirements of battery heat dissipation performance, a coupled numerical simulation model for BTMS was established, which consists of a single cell heat production model and a composite phase change material (CPCM) heat transfer model. Secondly, the table of DOE was established using center composite inscribed design, and then the optimal design was obtained by response surface method and screening optimization algorithm. In the meantime, the effects of the thickness and composition of the expanded graphite/paraffin on the system performance were investigated. The results indicate that compared with the original design, the optimized design can reduce the system mass by 62.7%, the volume by 33.3%, the maximum temperature by 10.8%, and the maximum temperature difference is less than 5 ℃.
  • XU Jieyan, YANG Handi, CHENG Zhijiang, SHI Kunhong, LI Yongdong
    Chinese Journal of Power Sources. 2021, 45(8): 1077-1081. https://doi.org/10.3969/j.issn.1002-087X.2021.08.031
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    The modular multilevel hybrid converter (MMHC) battery energy storage system (BESS) with the goal of high integration in physical structure and function can be directly integrated into the medium and low voltage AC grid, which has higher efficiency and lower cost than other battery energy storage systems. The advantages of this are conducive to solving the intermittent and uncertain problems of the output of the distributed new energy generation side and realizing the peak-shaving and valley-filling of the user-side load. Based on the characteristics of the MMHC-BESS topology, the modulation strategy of MHHC-BESS is given. Aiming at the problem of poor estimation of the state of charge (SOC) of the battery using the ampere-hour integration method and the open circuit voltage method for the battery pack in the multi-level converter battery energy storage system, and the problem of the energy utilization rate of MMHC-BESS, respectively. A closed-loop SOC estimation strategy and a two-layer SOC equalization strategy based on the extended Kalman battery model are proposed, which realizes the accurate estimation of the SOC of all battery packs in MMHC-BESS and the SOC balance of all battery pack modules in phases and phases of MMHC-BESS. A simulation model is used to verify the effectiveness of the proposed SOC estimation method and equilibrium strategy.
  • LIU Zhengxin, DU Jiuyu, YU Boyang
    Chinese Journal of Power Sources. 2021, 45(8): 1082-1086. https://doi.org/10.3969/j.issn.1002-087X.2021.08.032
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    Fuel cells, photovoltaic power generation and high voltage charging system of electric vehicles need high boost ratio DC / DC converter. The common non isolated DC / DC converter has low boost, which is difficult to meet the actual demand. According to this problem, this paper proposes a three-switch dual Boost high-gain DC/DC converter with a simple structure and high power density. On the basis of analyzing the operating principle of the proposed converter, a small signal model of the converter is established by the state-space averaging method, and a double closed-loop PI controller is designed. The experimental results show that the proposed DC/DC converter can achieve a boost ratio of more than 8, which is suitable for a wide input voltage range and high gain requirements. In terms of system efficiency, the proposed DC/DC converter with three-switch double Boost structure achieves a maximum efficiency of 95.18% compared to the traditional Boost converter, and the efficiency range is much smaller than that of the traditional Boost converter under the same experimental conditions. In the double closed-loop PI control system, the proposed DC/DC converter has good robustness.
  • Review
  • HUANG Lili, LU Languang, LIU Lishuo, ZHAN Jinghua
    Chinese Journal of Power Sources. 2021, 45(8): 1087-1090. https://doi.org/10.3969/j.issn.1002-087X.2021.08.033
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    Commercial separators of lithium ion batteries in vehicles play an important role in battery safety, due to commercial polymer separators with low temperature of shutdown, melting and weak mechanical strength. Under the conditions of mechanical abuse, electrical abuse, and thermal abuse, separators are prone to fail in mechanical integrity and thermal stability, which in turn can cause internal short circuit and trigger thermal runaway. In this review, aiming at the problem of separator failures, this paper introduces the basic properties and functions of commercial separators in lithium ion batteries, summarizes the mechanism, causes and forms of separator failures, and proposes improvement measures of separator properties and preventions for separator failures. Finally, the future research is prospected.
  • WANG Ruidi, ZHAO Xin, HAO Dong
    Chinese Journal of Power Sources. 2021, 45(8): 1091-1094. https://doi.org/10.3969/j.issn.1002-087X.2021.08.034
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    Visualization technology is one of the important technologies for the study of water management in proton exchange membrane fuel cell (PEMFC). Starting from the research significance of visualized PEMFC, the review of visualized PEMFC is summarized. The advantage and existing problems of the visualized PEMFC methods are introduced. The problems in the experiment of visualized PEMFC are discussed, and the potential solutions are proposed. It has guiding significance to improve the visualization technology of single cell.
  • ZHU Hao, LIU Muxiao, TIAN Yumeng
    Chinese Journal of Power Sources. 2021, 45(8): 1095-1099. https://doi.org/10.3969/j.issn.1002-087X.2021.08.035
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    The performance of thermal battery is determined by the properties of cathode materials. With the development of military equipment, the importance of weapon power supply is increasing, and the existing thermal battery system has been difficult to meet the requirements of modern combat readiness weapons equipment for battery performance. In this paper, the research status and modification schemes of NiCl2 cathode materials are reviewed, and the development trend of NiCl2 as high power cathode materials is prospected.